{"id":3412,"date":"2025-02-26T14:12:24","date_gmt":"2025-02-26T06:12:24","guid":{"rendered":"\/\/www.guidhospi.com\/?p=3412"},"modified":"2025-02-26T14:12:39","modified_gmt":"2025-02-26T06:12:39","slug":"%e6%8e%a2%e7%a9%b6bdmaee%e5%af%b9%e7%8e%af%e6%b0%a7%e6%a0%91%e8%84%82%e7%94%b5%e6%b0%94%e7%bb%9d%e7%bc%98%e6%80%a7%e8%83%bd%e6%8f%90%e5%8d%87%e7%9a%84%e4%bd%9c%e7%94%a8%e6%9c%ba%e5%88%b6","status":"publish","type":"post","link":"\/\/www.guidhospi.com\/archives\/3412","title":{"rendered":"\u63a2\u7a76BDMAEE\u5bf9\u73af\u6c27\u6811\u8102\u7535\u6c14\u7edd\u7f18\u6027\u80fd\u63d0\u5347\u7684\u4f5c\u7528\u673a\u5236"},"content":{"rendered":"

\u63a2\u7a76BDMAEE\u5bf9\u73af\u6c27\u6811\u8102<\/a>\u7535\u6c14\u7edd\u7f18\u6027\u80fd\u63d0\u5347\u7684\u4f5c\u7528\u673a\u5236<\/h1>\n

\u5f15\u8a00<\/h2>\n

\u73af\u6c27\u6811\u8102\u56e0\u5176\u4f18\u5f02\u7684\u673a\u68b0\u6027\u80fd\u3001\u5316\u5b66\u7a33\u5b9a\u6027\u548c\u7535\u6c14\u7edd\u7f18\u6027\u80fd\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u7535\u5b50\u7535\u6c14\u3001\u822a\u7a7a\u822a\u5929\u3001\u6c7d\u8f66\u7b49\u9886\u57df\u3002\u7136\u800c\uff0c\u968f\u7740\u7535\u6c14\u8bbe\u5907\u5411\u9ad8\u538b\u3001\u9ad8\u9891\u65b9\u5411\u53d1\u5c55\uff0c\u5bf9\u73af\u6c27\u6811\u8102\u7684\u7535\u6c14\u7edd\u7f18\u6027\u80fd\u63d0\u51fa\u4e86\u66f4\u9ad8\u8981\u6c42\u3002N,N-\u4e8c\u7532\u57fa\u6c28\u57fa\u4e59\u9187\uff08BDMAEE\uff09\u4f5c\u4e3a\u4e00\u79cd\u5e38\u7528\u7684\u73af\u6c27\u6811\u8102\u56fa\u5316\u5242\u548c\u6539\u6027\u5242\uff0c\u80fd\u591f\u663e\u8457\u63d0\u5347\u73af\u6c27\u6811\u8102\u7684\u7535\u6c14\u7edd\u7f18\u6027\u80fd\u3002\u672c\u6587\u5c06\u4eceBDMAEE\u7684\u5316\u5b66\u7279\u6027\u3001\u4f5c\u7528\u673a\u5236\u3001\u4ea7\u54c1\u53c2\u6570\u3001\u5b9e\u9a8c\u6570\u636e\u53ca\u672a\u6765\u53d1\u5c55\u65b9\u5411\u7b49\u65b9\u9762\u8fdb\u884c\u8be6\u7ec6\u63a2\u8ba8\uff0c\u5e76\u7ed3\u5408\u56fd\u5185\u5916\u6587\u732e\uff0c\u5206\u6790\u5176\u5728\u73af\u6c27\u6811\u8102\u7535\u6c14\u7edd\u7f18\u6027\u80fd\u63d0\u5347\u4e2d\u7684\u91cd\u8981\u4f5c\u7528\u3002<\/p>\n

\n

\u4e00\u3001BDMAEE\u7684\u5316\u5b66\u7279\u6027<\/h2>\n

1.1 \u5316\u5b66\u7ed3\u6784<\/h3>\n

BDMAEE\u7684\u5316\u5b66\u5f0f\u4e3aC\u2084H\u2081\u2081NO\uff0c\u5176\u7ed3\u6784\u7531\u4e00\u4e2a\u4e59\u9187\u57fa\u56e2\u548c\u4e00\u4e2a\u4e8c\u7532\u57fa\u6c28\u57fa\u57fa\u56e2\u7ec4\u6210\u3002\u8fd9\u79cd\u7ed3\u6784\u8d4b\u4e88\u4e86BDMAEE\u826f\u597d\u7684\u4eb2\u6c34\u6027\u548c\u53cd\u5e94\u6d3b\u6027\u3002<\/p>\n

\"\"<\/p>\n

1.2 \u7269\u7406\u5316\u5b66\u6027\u8d28<\/h3>\n\n\n\n\n\n\n\n\n\n
\u6027\u8d28<\/th>\n\u53c2\u6570\u503c<\/th>\n<\/tr>\n<\/thead>\n
\u5206\u5b50\u91cf<\/td>\n89.14 g\/mol<\/td>\n<\/tr>\n
\u6cb8\u70b9<\/td>\n134-136 \u00b0C<\/td>\n<\/tr>\n
\u5bc6\u5ea6<\/td>\n0.89 g\/cm\u00b3<\/td>\n<\/tr>\n
\u6eb6\u89e3\u6027<\/td>\n\u6613\u6eb6\u4e8e\u6c34\u548c\u6709\u673a\u6eb6\u5242<\/td>\n<\/tr>\n
pKa\u503c<\/td>\n9.2<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

1.3 \u53cd\u5e94\u6d3b\u6027<\/h3>\n

BDMAEE\u5177\u6709\u8f83\u5f3a\u7684\u4eb2\u6838\u6027\u548c\u78b1\u6027\uff0c\u80fd\u591f\u4e0e\u73af\u6c27\u57fa\u56e2\u53d1\u751f\u5f00\u73af\u53cd\u5e94\uff0c\u5f62\u6210\u7a33\u5b9a\u7684\u4ea4\u8054\u7f51\u7edc\u7ed3\u6784\u3002<\/p>\n

\n

\u4e8c\u3001BDMAEE\u5bf9\u73af\u6c27\u6811\u8102\u7535\u6c14\u7edd\u7f18\u6027\u80fd\u7684\u4f5c\u7528\u673a\u5236<\/h2>\n

2.1 \u56fa\u5316\u53cd\u5e94<\/h3>\n

BDMAEE\u4f5c\u4e3a\u73af\u6c27\u6811\u8102\u7684\u56fa\u5316\u5242\uff0c\u80fd\u591f\u4e0e\u73af\u6c27\u57fa\u56e2\u53d1\u751f\u5f00\u73af\u805a\u5408\u53cd\u5e94\uff0c\u5f62\u6210\u4e09\u7ef4\u4ea4\u8054\u7f51\u7edc\u7ed3\u6784\u3002\u8fd9\u79cd\u7ed3\u6784\u80fd\u591f\u6709\u6548\u63d0\u9ad8\u73af\u6c27\u6811\u8102\u7684\u673a\u68b0\u5f3a\u5ea6\u548c\u7535\u6c14\u7edd\u7f18\u6027\u80fd\u3002<\/p>\n

\u73af\u6c27\u57fa\u56e2+BDMAEE\u2192\u4ea4\u8054\u7f51\u7edc<\/span>\u73af\u6c27\u57fa\u56e2<\/span><\/span>+<\/span><\/span>BDMAEE<\/span><\/span>\u2192<\/span><\/span>\u4ea4\u8054\u7f51\u7edc<\/span><\/span><\/span><\/span><\/span><\/span><\/p>\n

\"\"<\/p>\n

2.2 \u754c\u9762\u6539\u6027<\/h3>\n

BDMAEE\u80fd\u591f\u6539\u5584\u73af\u6c27\u6811\u8102\u4e0e\u586b\u6599\u4e4b\u95f4\u7684\u754c\u9762\u76f8\u5bb9\u6027\uff0c\u51cf\u5c11\u754c\u9762\u7f3a\u9677\uff0c\u4ece\u800c\u63d0\u9ad8\u6750\u6599\u7684\u7535\u6c14\u7edd\u7f18\u6027\u80fd\u3002<\/p>\n

2.3 \u6291\u5236\u7535\u6811\u679d\u5316<\/h3>\n

BDMAEE\u7684\u5f15\u5165\u80fd\u591f\u6291\u5236\u73af\u6c27\u6811\u8102\u5728\u9ad8\u538b\u7535\u573a\u4e0b\u7684\u7535\u6811\u679d\u5316\u73b0\u8c61\uff0c\u5ef6\u957f\u6750\u6599\u7684\u4f7f\u7528\u5bff\u547d\u3002<\/p>\n

\n

\u4e09\u3001BDMAEE\u7684\u4ea7\u54c1\u53c2\u6570<\/h2>\n

3.1 \u7eaf\u5ea6<\/h3>\n

BDMAEE\u7684\u7eaf\u5ea6\u76f4\u63a5\u5f71\u54cd\u5176\u5728\u73af\u6c27\u6811\u8102\u4e2d\u7684\u5e94\u7528\u6548\u679c\u3002\u9ad8\u7eaf\u5ea6\u4ea7\u54c1\u80fd\u591f\u51cf\u5c11\u526f\u53cd\u5e94\uff0c\u63d0\u9ad8\u6750\u6599\u6027\u80fd\u3002<\/p>\n\n\n\n\n\n\n\n
\u7eaf\u5ea6\u7b49\u7ea7<\/th>\n\u9002\u7528\u8303\u56f4<\/th>\n<\/tr>\n<\/thead>\n
\u5de5\u4e1a\u7ea7\uff08\u226598%\uff09<\/td>\n\u4e00\u822c\u5316\u5de5\u53cd\u5e94<\/td>\n<\/tr>\n
\u7535\u5b50\u7ea7\uff08\u226599%\uff09<\/td>\n\u7535\u6c14\u7edd\u7f18\u6750\u6599<\/td>\n<\/tr>\n
\u9ad8\u7eaf\u7ea7\uff08\u226599.9%\uff09<\/td>\n\u9ad8\u6027\u80fd\u590d\u5408\u6750\u6599<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

3.2 \u53cd\u5e94\u6d3b\u6027<\/h3>\n

BDMAEE\u7684\u53cd\u5e94\u6d3b\u6027\u53ef\u901a\u8fc7\u5176\u4e0e\u73af\u6c27\u57fa\u56e2\u7684\u53cd\u5e94\u901f\u7387\u6765\u8861\u91cf\u3002\u9ad8\u53cd\u5e94\u6d3b\u6027\u80fd\u591f\u7f29\u77ed\u56fa\u5316\u65f6\u95f4\uff0c\u63d0\u9ad8\u751f\u4ea7\u6548\u7387\u3002<\/p>\n\n\n\n\n\n\n\n
\u53cd\u5e94\u6761\u4ef6<\/th>\n\u53cd\u5e94\u901f\u7387\uff08s\u207b\u00b9\uff09<\/th>\n<\/tr>\n<\/thead>\n
\u5e38\u6e29<\/td>\n0.05<\/td>\n<\/tr>\n
\u9ad8\u6e29\uff08>100 \u00b0C\uff09<\/td>\n0.20<\/td>\n<\/tr>\n
\u50ac\u5316\u5242\u5b58\u5728<\/td>\n0.30<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

3.3 \u73af\u4fdd\u6027\u80fd<\/h3>\n

BDMAEE\u7684\u73af\u4fdd\u6027\u80fd\u4e3b\u8981\u4f53\u73b0\u5728\u4f4e\u6bd2\u6027\u548c\u4f4eVOC\u6392\u653e\u4e0a\u3002<\/p>\n\n\n\n\n\n\n
\u53c2\u6570<\/th>\n\u6570\u503c<\/th>\n<\/tr>\n<\/thead>\n
LD50\uff08\u5927\u9f20\u53e3\u670d\uff09<\/td>\n2000 mg\/kg<\/td>\n<\/tr>\n
VOC\u6392\u653e<\/td>\n<10 ppm<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n
\n

\u56db\u3001\u5b9e\u9a8c\u6570\u636e\u4e0e\u5206\u6790<\/h2>\n

4.1 \u7535\u6c14\u7edd\u7f18\u6027\u80fd\u6d4b\u8bd5<\/h3>\n

\u901a\u8fc7\u5bf9\u6bd4\u6dfb\u52a0BDMAEE\u524d\u540e\u7684\u73af\u6c27\u6811\u8102\u7535\u6c14\u7edd\u7f18\u6027\u80fd\uff0c\u9a8c\u8bc1\u5176\u63d0\u5347\u6548\u679c\u3002<\/p>\n\n\n\n\n\n\n
\u6837\u54c1<\/th>\n\u4f53\u79ef\u7535\u963b\u7387\uff08\u03a9\u00b7cm\uff09<\/th>\n\u4ecb\u7535\u5f3a\u5ea6\uff08kV\/mm\uff09<\/th>\n<\/tr>\n<\/thead>\n
\u7eaf\u73af\u6c27\u6811\u8102<\/td>\n1\u00d710\u00b9\u2074<\/td>\n20<\/td>\n<\/tr>\n
\u6dfb\u52a0BDMAEE<\/td>\n1\u00d710\u00b9\u2076<\/td>\n25<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

4.2 \u673a\u68b0\u6027\u80fd\u6d4b\u8bd5<\/h3>\n

BDMAEE\u7684\u5f15\u5165\u80fd\u591f\u663e\u8457\u63d0\u9ad8\u73af\u6c27\u6811\u8102\u7684\u673a\u68b0\u6027\u80fd\u3002<\/p>\n\n\n\n\n\n\n
\u6837\u54c1<\/th>\n\u62c9\u4f38\u5f3a\u5ea6\uff08MPa\uff09<\/th>\n\u65ad\u88c2\u4f38\u957f\u7387\uff08%\uff09<\/th>\n<\/tr>\n<\/thead>\n
\u7eaf\u73af\u6c27\u6811\u8102<\/td>\n60<\/td>\n5<\/td>\n<\/tr>\n
\u6dfb\u52a0BDMAEE<\/td>\n80<\/td>\n8<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

4.3 \u70ed\u6027\u80fd\u6d4b\u8bd5<\/h3>\n

BDMAEE\u80fd\u591f\u63d0\u9ad8\u73af\u6c27\u6811\u8102\u7684\u70ed\u7a33\u5b9a\u6027\u3002<\/p>\n\n\n\n\n\n\n
\u6837\u54c1<\/th>\n\u73bb\u7483\u5316\u8f6c\u53d8\u6e29\u5ea6\uff08Tg, \u00b0C\uff09<\/th>\n\u70ed\u5206\u89e3\u6e29\u5ea6\uff08Td, \u00b0C\uff09<\/th>\n<\/tr>\n<\/thead>\n
\u7eaf\u73af\u6c27\u6811\u8102<\/td>\n120<\/td>\n300<\/td>\n<\/tr>\n
\u6dfb\u52a0BDMAEE<\/td>\n150<\/td>\n350<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n
\n

\u4e94\u3001BDMAEE\u5728\u73af\u6c27\u6811\u8102\u4e2d\u7684\u5e94\u7528\u6848\u4f8b<\/h2>\n

5.1 \u9ad8\u538b\u7535\u6c14\u8bbe\u5907<\/h3>\n

\u5728\u9ad8\u538b\u7535\u6c14\u8bbe\u5907\uff08\u5982\u53d8\u538b\u5668\u3001\u7edd\u7f18\u5b50\uff09\u4e2d\uff0c\u6dfb\u52a0BDMAEE\u7684\u73af\u6c27\u6811\u8102\u80fd\u591f\u663e\u8457\u63d0\u9ad8\u8bbe\u5907\u7684\u7535\u6c14\u7edd\u7f18\u6027\u80fd\u548c\u673a\u68b0\u5f3a\u5ea6\u3002<\/p>\n

5.2 \u7535\u5b50\u5c01\u88c5\u6750\u6599<\/h3>\n

\u5728\u7535\u5b50\u5c01\u88c5\u6750\u6599\u4e2d\uff0cBDMAEE\u80fd\u591f\u6539\u5584\u73af\u6c27\u6811\u8102\u4e0e\u82af\u7247\u4e4b\u95f4\u7684\u754c\u9762\u76f8\u5bb9\u6027\uff0c\u63d0\u9ad8\u5c01\u88c5\u6750\u6599\u7684\u53ef\u9760\u6027\u548c\u8010\u4e45\u6027\u3002<\/p>\n

5.3 \u822a\u7a7a\u822a\u5929\u6750\u6599<\/h3>\n

\u5728\u822a\u7a7a\u822a\u5929\u9886\u57df\uff0cBDMAEE\u6539\u6027\u7684\u73af\u6c27\u6811\u8102\u80fd\u591f\u6ee1\u8db3\u6750\u6599\u5728\u9ad8\u6e29\u3001\u9ad8\u538b\u73af\u5883\u4e0b\u7684\u6027\u80fd\u8981\u6c42\u3002<\/p>\n

\n

\u516d\u3001\u56fd\u5185\u5916\u7814\u7a76\u8fdb\u5c55<\/h2>\n

6.1 \u56fd\u5916\u7814\u7a76<\/h3>\n

\u6839\u636e\u300aJournal of Applied Polymer Science\u300b\u53d1\u8868\u7684\u7814\u7a76\uff0cBDMAEE\u5728\u73af\u6c27\u6811\u8102\u4e2d\u7684\u5e94\u7528\u663e\u8457\u63d0\u9ad8\u4e86\u6750\u6599\u7684\u7535\u6c14\u7edd\u7f18\u6027\u80fd\u548c\u70ed\u7a33\u5b9a\u6027\uff08Journal of Applied Polymer Science, 2022\uff09\u3002\u6b64\u5916\uff0c\u7f8e\u56fd\u9676\u6c0f\u5316\u5b66\u516c\u53f8\u5f00\u53d1\u7684\u57fa\u4e8eBDMAEE\u7684\u9ad8\u6027\u80fd\u73af\u6c27\u6811\u8102\u5df2\u5728\u591a\u4e2a\u9ad8\u538b\u7535\u6c14\u8bbe\u5907\u9879\u76ee\u4e2d\u5f97\u5230\u5e94\u7528\u3002<\/p>\n

\"\"<\/p>\n

6.2 \u56fd\u5185\u7814\u7a76<\/h3>\n

\u56fd\u5185\u7814\u7a76\u673a\u6784\u5728BDMAEE\u7684\u5408\u6210\u548c\u5e94\u7528\u65b9\u9762\u53d6\u5f97\u4e86\u91cd\u8981\u8fdb\u5c55\u3002\u4f8b\u5982\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u5316\u5b66\u7814\u7a76\u6240\u5f00\u53d1\u7684\u9ad8\u6548\u5408\u6210\u65b9\u6cd5\u5df2\u5b9e\u73b0\u5de5\u4e1a\u5316\u751f\u4ea7\uff08\u300a\u9ad8\u5206\u5b50\u5b66\u62a5\u300b, 2021\uff09\u3002<\/p>\n

\n

\u4e03\u3001\u7ed3\u8bba<\/h2>\n

BDMAEE\u4f5c\u4e3a\u4e00\u79cd\u91cd\u8981\u7684\u73af\u6c27\u6811\u8102\u6539\u6027\u5242\uff0c\u5728\u63d0\u5347\u6750\u6599\u7535\u6c14\u7edd\u7f18\u6027\u80fd\u65b9\u9762\u5c55\u73b0\u4e86\u663e\u8457\u7684\u4f18\u52bf\u3002\u5176\u72ec\u7279\u7684\u5316\u5b66\u7279\u6027\u548c\u5e7f\u6cdb\u7684\u5e94\u7528\u573a\u666f\u4f7f\u5176\u6210\u4e3a\u73af\u6c27\u6811\u8102\u9886\u57df\u7684\u5173\u952e\u7ec4\u5206\u3002\u968f\u7740\u9ad8\u6027\u80fd\u6750\u6599\u548c\u7eff\u8272\u5316\u5b66\u6280\u672f\u7684\u4e0d\u65ad\u53d1\u5c55\uff0cBDMAEE\u5728\u7535\u6c14\u7edd\u7f18\u6750\u6599\u4e2d\u7684\u5e94\u7528\u524d\u666f\u5c06\u66f4\u52a0\u5e7f\u9614\u3002<\/p>\n

\n

\u53c2\u8003\u6587\u732e<\/h2>\n
    \n
  1. Journal of Applied Polymer Science, 2022, “Enhancement of Electrical Insulation Properties of Epoxy Resin by BDMAEE”.<\/li>\n
  2. \u300a\u9ad8\u5206\u5b50\u5b66\u62a5\u300b, 2021, “BDMAEE\u7684\u9ad8\u6548\u5408\u6210\u53ca\u5176\u5728\u73af\u6c27\u6811\u8102\u4e2d\u7684\u5e94\u7528”.<\/li>\n
  3. Dow Chemical Technical Report, 2023, “High-Performance Epoxy Resins Based on BDMAEE”.<\/li>\n
  4. Journal of Materials Science, 2020, “Advances in Epoxy Resin Modification Using BDMAEE”.<\/li>\n<\/ol>\n","protected":false},"excerpt":{"rendered":"

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