{"id":2238,"date":"2024-07-22T15:03:39","date_gmt":"2024-07-22T07:03:39","guid":{"rendered":"\/\/www.guidhospi.com\/?p=2238"},"modified":"2024-07-22T16:00:54","modified_gmt":"2024-07-22T08:00:54","slug":"stille%e5%81%b6%e8%81%94%e5%8f%8d%e5%ba%94","status":"publish","type":"post","link":"\/\/www.guidhospi.com\/archives\/2238","title":{"rendered":"Stille\u5076\u8054\u53cd\u5e94"},"content":{"rendered":"<p><a href=\"\/\/www.guidhospi.com\/\" target=\"_self\" rel=\"noopener\"><strong>Stille\u5076\u8054\u53cd\u5e94<\/strong><\/a><\/p>\n<p>Stille\u5076\u8054\u53cd\u5e94\u662f\u6307\u6709\u673a\u9521\u8bd5\u5242\u548c\u5364\u4ee3\u7269\u6216\u7c7b\u5364\u4ee3\u7269\u5728\u94af\u50ac\u5316\u4e0b\u8fdb\u884cCC\u952e\u5076\u8054\u7684\u53cd\u5e94\u3002\u6b64\u53cd\u5e94\u5bf9\u5364\u4ee3\u7269\u7684R\u57fa\u56e2\u9650\u5236\u8f83\u5c11\u3002\u53cd\u5e94\u7684\u6761\u4ef6\u6bd4\u8f83\u591a\uff0c\u53e6\u5916\u6b63\u5982\u4e0b\u65b9\u4ecb\u7ecd\u7684\u5364\u4ee3\u7269\u548c\u6709\u673a\u9521\u8bd5\u5242\u79cd\u7c7b\u5f88\u591a\uff0c\u4e92\u76f8\u8fdb\u884c\u5076\u8054\uff0c\u56e0\u6b64\u6b64\u53cd\u5e94\u53ef\u4ee5\u5408\u6210\u7684\u4ea7\u7269\u4e5f\u5f88\u591a\u3002\u672c\u53cd\u5e94\u7684\u7f3a\u70b9\u5c31\u662f\uff0c\u6709\u673a\u9521\u8bd5\u5242\u6bd2\u6027\u8f83\u5927\uff0c\u800c\u4e14\u5176\u6781\u6027\u8f83\u5c0f\uff0c\u5728\u6c34\u4e2d\u7684\u6eb6\u89e3\u5ea6\u5f88\u4f4e\u3002\u867d\u7136\u6709\u673a\u9521\u8bd5\u5242\u5f88\u7a33\u5b9a\uff0c\u4f46\u662f\u7531\u4e8e\u4e0eStille\u5076\u8054\u51e0\u4e4e\u76f8\u540c\u7684Suzuki \u53cd\u5e94\u7684\u53d1\u73b0\uff0cSuzuki \u53cd\u5e94\u4f7f\u7528\u6709\u673a\u787c\u9178\u53ca\u5176\u884d\u751f\u7269\uff0c\u4f7f\u7528\u65b9\u4fbf\u5e76\u4e14\u6ca1\u6709\u6709\u673a\u9521\u8bd5\u5242\u7684\u90a3\u4e9b\u7f3a\u70b9\uff0c\u56e0\u6b64\u6b64\u53cd\u5e94\u7684\u91cd\u8981\u6027\u8fc5\u901f\u964d\u4f4e\u3002<\/p>\n<p><img decoding=\"async\" class=\"alignnone size-full wp-image-2239\" src=\"\/\/www.guidhospi.com\/wp-content\/uploads\/2024\/07\/1701512784791-4.jpg\" width=\"1080\" height=\"1080\" srcset=\"\/\/www.guidhospi.com\/wp-content\/uploads\/2024\/07\/1701512784791-4.jpg 1080w, \/\/www.guidhospi.com\/wp-content\/uploads\/2024\/07\/1701512784791-4-300x300.jpg 300w, \/\/www.guidhospi.com\/wp-content\/uploads\/2024\/07\/1701512784791-4-1024x1024.jpg 1024w, \/\/www.guidhospi.com\/wp-content\/uploads\/2024\/07\/1701512784791-4-150x150.jpg 150w, \/\/www.guidhospi.com\/wp-content\/uploads\/2024\/07\/1701512784791-4-768x768.jpg 768w\" sizes=\"(max-width: 1080px) 100vw, 1080px\" \/><\/p>\n<p>Stille-Kelly\u53cd\u5e94<\/p>\n<p>\u94af\u50ac\u5316\u4e0b\u5206\u5b50\u5185\u7684\u4e8c\u82b3\u57fa\u5364\u4ee3\u7269\u5229\u7528\u4e8c\u9521\u8bd5\u5242\u8fdb\u884c\u4ea4\u53c9\u5076\u8054\u7684\u53cd\u5e94\u3002<\/p>\n<p>Stille\u7fb0\u57fa\u5316\u5076\u8054\u53cd\u5e94<\/p>\n<p>\u6b64\u53cd\u5e94\u7531Migita\u548cStille\u5f00\u53d1\uff0c\u5229\u7528\u9170\u6c2f\u8fdb\u884cStille\u5076\u8054\u53cd\u5e94\u5236\u5907\u916e\u3002\u4f46\u662f\u9170\u6c2f\u901a\u5e38\u4e0d\u7a33\u5b9a\u800c\u4e14\u5bf9\u4e8e\u6d3b\u6027\u5b98\u80fd\u56e2\u4e0d\u517c\u5bb9\uff0c\u9650\u5236\u4e86\u5176\u5e94\u7528\u8303\u56f4\u3002\u5728\u4e0a\u4e16\u7eaa80\u5e74\u4ee3\uff0c\u5728\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u4e0b\u6709\u673a\u5364\u4ee3\u70c3\u548c\u7c7b\u5364\u4ee3\u70c3\u8fdb\u884c\u7fb0\u57fa\u5316\u5076\u8054\u53cd\u5e94\u5236\u5907\u916e\u7684\u65b9\u6cd5\u88ab\u5f00\u53d1\u51fa\u6765\u3002Pd(0)\u50ac\u5316\u4e0b\uff0c\u6709\u673a\u9521\u8bd5\u5242\uff0c\u4e00\u6c27\u5316\u78b3\u548c\u6709\u673a\u4eb2\u7535\u8bd5\u5242\uff08\u82b3\u57fa\u6216\u70ef\u57fa\u5364\u4ee3\u70c3\u548c\u82b3\u57fa\u6216\u70ef\u57fa\u7c7b\u5364\u4ee3\u70c3\uff09\u5076\u8054\u5f62\u6210\u65b0\u7684\u78b3\u78b3\u5355\u952e\u7684\u53cd\u5e94\uff0c\u88ab\u79f0\u4e3aStille\u7fb0\u57fa\u5316\u5076\u8054\u53cd\u5e94\u3002<\/p>\n<p><img decoding=\"async\" class=\"alignnone size-full wp-image-2240\" src=\"\/\/www.guidhospi.com\/wp-content\/uploads\/2024\/07\/1688270266158-1.jpg\" width=\"800\" height=\"600\" srcset=\"\/\/www.guidhospi.com\/wp-content\/uploads\/2024\/07\/1688270266158-1.jpg 800w, \/\/www.guidhospi.com\/wp-content\/uploads\/2024\/07\/1688270266158-1-300x225.jpg 300w, \/\/www.guidhospi.com\/wp-content\/uploads\/2024\/07\/1688270266158-1-768x576.jpg 768w\" sizes=\"(max-width: 800px) 100vw, 800px\" \/><\/p>\n<p>Tsuji-Trost\u53cd\u5e94<\/p>\n<p>\u94af\u50ac\u5316\u4e0b\u5229\u7528\u70ef\u4e19\u57fa\u5316\u5408\u7269\uff08\u5982\u4e59\u9178\u70ef\u4e19\u916f\u548c\u70ef\u4e19\u57fa\u6eb4\uff09\u5bf9\u4eb2\u6838\u8bd5\u5242\uff08\u5982\u6d3b\u6027\u4e9a\u7532\u57fa\u5316\u5408\u7269\uff0c\u70ef\u9187\u5316\u5408\u7269\uff0c\u80fa\u548c\u915a\uff09\u8fdb\u884c\u70ef\u4e19\u57fa\u5316\u7684\u53cd\u5e94\u3002<\/p>\n<p>Catellani\u53cd\u5e94<\/p>\n<p>\u3010Catellani, M.; Frignani, F.; Rangoni, A. Angew. Chem. Int. Ed. 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