{"id":2233,"date":"2024-07-22T14:49:41","date_gmt":"2024-07-22T06:49:41","guid":{"rendered":"\/\/www.guidhospi.com\/?p=2233"},"modified":"2024-07-22T16:01:17","modified_gmt":"2024-07-22T08:01:17","slug":"%e5%b8%b8%e8%a7%81%e9%87%91%e5%b1%9e%e5%82%ac%e5%8c%96%e5%8f%8d%e5%ba%94%e6%b1%87%e6%80%bb","status":"publish","type":"post","link":"\/\/www.guidhospi.com\/archives\/2233","title":{"rendered":"\u5e38\u89c1\u91d1\u5c5e\u50ac\u5316\u53cd\u5e94\u6c47\u603b"},"content":{"rendered":"

\u5e38\u89c1\u91d1\u5c5e\u50ac\u5316\u53cd\u5e94\u6c47\u603b<\/strong><\/a><\/p>\n

\u91d1\u5c5e\u50ac\u5316\u7684\u5076\u8054\u53cd\u5e94\u662f\u6709\u673a\u5408\u6210\u4e2d\u5e38\u89c1\u7684\u5f62\u6210\u78b3\u78b3\u952e\u548c\u78b3\u6742\u952e\u7684\u53cd\u5e94\uff0c\u5728\u6709\u673a\u5408\u6210\u4e2d\u6709\u7740\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\u3002<\/p>\n

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\u4e00\u3001\u94af\u50ac\u5316\u7c7b<\/p>\n

1\u3001Suzuki\u2013Miyaura\u53cd\u5e94<\/p>\n

Suzuki\u53cd\u5e94\uff08\u94c3\u6728\u53cd\u5e94\uff09\uff0c\u4e5f\u79f0\u4f5cSuzuki\u5076\u8054\u53cd\u5e94\u3001Suzuki-Miyaura\u53cd\u5e94\uff08\u94c3\u6728\uff0d\u5bab\u6d66\u53cd\u5e94\uff09\uff0c\u662f\u4e00\u4e2a\u8f83\u65b0\u7684\u6709\u673a\u5076\u8054\u53cd\u5e94\uff0c\u96f6\u4ef7\u94af\u914d\u5408\u7269\u50ac\u5316\u4e0b\uff0c\u82b3\u57fa\u6216\u70ef\u57fa\u787c\u9178\u6216\u787c\u9178\u916f\u4e0e\u6c2f\u3001\u6eb4\u3001\u7898\u4ee3\u82b3\u70c3\u6216\u70ef\u70c3\u53d1\u751f\u4ea4\u53c9\u5076\u8054\u3002\u8be5\u53cd\u5e94\u7531\u94c3\u6728\u7ae0\u57281979\u5e74\u9996\u5148\u62a5\u9053\uff0c\u5728\u6709\u673a\u5408\u6210\u4e2d\u7684\u7528\u9014\u5f88\u5e7f\uff0c\u5177\u5f3a\u7684\u5e95\u7269\u9002\u5e94\u6027\u53ca\u5b98\u80fd\u56e2\u5bb9\u5fcd\u6027\uff0c\u5e38\u7528\u4e8e\u5408\u6210\u591a\u70ef\u70c3\u3001\u82ef\u4e59\u70ef\u548c\u8054\u82ef\u7684\u884d\u751f\u7269\uff0c\u4ece\u800c\u5e94\u7528\u4e8e\u4f17\u591a\u5929\u7136\u4ea7\u7269\u3001\u6709\u673a\u6750\u6599\u7684\u5408\u6210\u4e2d\u3002\u94c3\u6728\u7ae0\u4e5f\u51ed\u501f\u6b64\u8d21\u732e\u4e0e\u7406\u67e5\u5fb7\u00b7\u8d6b\u514b\u3001\u6839\u5cb8\u82f1\u4e00\u5171\u540c\u83b7\u5f972010\u5e74\u8bfa\u8d1d\u5c14\u5316\u5b66\u5956<\/p>\n

9-BBN\u53c2\u4e0e\u7684Suzuki\u53cd\u5e94\u5b9e\u4f8b<\/p>\n

\u65e0\u81a6\u914d\u4f53\u94af\u50ac\u5316\u5242\u50ac\u5316\u7684Suzuki\u53cd\u5e94<\/p>\n

\u82b3\u57fa\u6c2f\u53c2\u4e0eSuzuki\u5076\u8054\u53cd\u5e94<\/p>\n

\u70f7\u57fa\u6c1f\u787c\u9178\u94be\u53c2\u4e0eSuzuki\u5076\u8054\u53cd\u5e94\u793a\u4f8b<\/p>\n

<\/p>\n

2\u3001Miyaura\u787c\u9178\u916f\u5316\u53cd\u5e94<\/p>\n

\u94af\u50ac\u5316\u4e0b\u82b3\u57fa\u5364\u4ee3\u7269\u548c\u53cc\u8054\u787c\u8bd5\u5242\u53cd\u5e94\u5236\u5907\u82b3\u57fa\u787c\u9178\u916f\u7684\u53cd\u5e94\u3002\u4e5f\u88ab\u79f0\u4e3aHosomi-Miyaura\u787c\u9178\u5316\u53cd\u5e94\u3002<\/p>\n

\u91d1\u5c5e\u6709\u673a\u8bd5\u5242\u5236\u5907\u5355\u53d6\u4ee3\u82b3\u57fa\u787c\u9178<\/p>\n

\u6709\u673a\u787c\u9178\u53ca\u5176\u884d\u751f\u7269\u7684\u5236\u5907\u793a\u4f8b<\/p>\n

3\u3001Buchwald-Hartwig\u53cd\u5e94<\/p>\n

Buchwald\u2013Hartwig\u82b3\u80fa\u5316\u53cd\u5e94\u662f\u975e\u5e38\u5e38\u7528\u7684\u7531\u82b3\u57fa\u5364\u4ee3\u7269\u6216\u82b3\u57fa\u78fa\u9178\u916f\u5236\u5907\u82b3\u80fa\u7684\u53cd\u5e94\u3002\u6b64\u53cd\u5e94\u7684\u4e3b\u8981\u7279\u70b9\u662f\u5229\u7528\u50ac\u5316\u91cf\u7684\u94af\u548c\u5bcc\u7535\u5b50\u914d\u4f53\u8fdb\u884c\u50ac\u5316\u53cd\u5e94\u3002\u53e6\u5916\u5f3a\u78b1\uff08\u5982\u53d4\u4e01\u9187\u94a0\uff09\u5bf9\u4e8e\u50ac\u5316\u5faa\u73af\u662f\u81f3\u5173\u91cd\u8981\u7684\u3002<\/p>\n

Buchwald\u2013HartwigC-N\u5076\u8054\u53cd\u5e94\u7b80\u4ecb<\/p>\n

Buchwald-Hartwig\u5076\u8054\u53cd\u5e94\u4e2d\u5e38\u89c1\u7684\u914d\u4f53<\/p>\n

Buchwald-Hartwig\u5076\u805425\u5468\u5e74\u5386\u7a0b<\/p>\n

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4\u3001Heck\u53cd\u5e94<\/p>\n

\u94af\u50ac\u5316\u4e0b\u5bf9\u70ef\u70c3\u8fdb\u884c\u70ef\u57fa\u6216\u82b3\u57fa\u5316\u7684\u53cd\u5e94\u3002\u53e6\u5916\u4e0d\u542b\u03b2\u6c22\u7684\u5364\u4ee3\u70c3\uff08\u4e3b\u8981\u662f\u5364\u5316\u82c4\uff09\u4e5f\u53ef\u53d1\u751fHeck\u53cd\u5e94\uff0c\u8fdb\u884c\u70f7\u57fa\u5316\u3002<\/p>\n

\u3010\u6709\u673a\u53cd\u5e94\u767e\u79d1\u3011Narasaka-Heck\u73af\u5316\u53cd\u5e94<\/p>\n

5\u3001\u82b3\u9999\u6742\u73afHeck\u53cd\u5e94<\/p>\n

\u82b3\u9999\u6742\u73af\u4f5c\u4e3a\u53d7\u4f53\u7684\u53d1\u751f\u5728\u5206\u5b50\u5185\u6216\u5206\u5b50\u95f4\u7684Heck\u53cd\u5e94\u3002<\/p>\n

6\u3001\u91cd\u6c2e\u76d0\u53c2\u4e0e\u7684Heck \u53cd\u5e94Image<\/p>\n

\u82b3\u57fa\u91cd\u6c2e\u76d0\u53ef\u4ee5\u53d1\u751f\u7684\u53cd\u5e94\u5e38\u89c1\u7684\u5c31\u662fSandmeyer\u53cd\u5e94\u53ef\u4ee5\u5236\u5907\u5364\u4ee3\u82b3\u70c3\uff0c\u82b3\u57fa\u915a\u6216\u82b3\u57fa\u8148\uff0c\u53e6\u5916\u5c31\u662fBalz-Schiemann\u53cd\u5e94\u5236\u5907\u82b3\u57fa\u6c1f\u5316\u7269\uff0c\u5076\u6c2e\u5076\u5408\u53cd\u5e94\u5236\u5907\u5076\u6c2e\u4e8c\u82b3\u57fa\u7c7b\u5316\u5408\u7269\u30021995\u5e74Beller\u7b49\u4eba\u62a5\u9053\u4e86\u5229\u7528\u91cd\u6c2e\u76d0\u4f5c\u4e3a\u5e95\u7269\u8fdb\u884cHeck\u53cd\u5e94\u5236\u5907\u82b3\u57fa\u70ef\u57fa\u5316\u7269\uff0c\u8fd9\u662f\u4e00\u79cd\u5f88\u5b9e\u7528\u7684\u5236\u5907\u82b3\u57fa\u70ef\u70c3\u7684\u53cd\u5e94\uff0c\u6b64\u7c7b\u53cd\u5e94\u4e0d\u9700\u8981\u81a6\u50ac\u5316\u5242\u548c\u80fa\uff0c\u6761\u4ef6\u6e29\u548c\u3002<\/p>\n

7\u3001Sonogashira\u53cd\u5e94<\/p>\n

Pd\/Cu\u50ac\u5316\u7684\u82b3\u5364\u6216\u70ef\u57fa\u5364\u4ee3\u7269\u548c\u7aef\u57fa\u7094\u8fdb\u884c\u5076\u8054\u7684\u53cd\u5e94\u3002\u53cd\u5e94\u673a\u7406\u548cCadiot\u2013Chodkiewicz\u5076\u8054\u4e0eCastro-?Stephens\u53cd\u5e94\u7c7b\u4f3c\u3002Castro-Stephens\u53cd\u5e94\u662f\u7528\u5316\u5b66\u5f53\u91cf\u7684\u94dc\u50ac\u5316\uff0c\u800cSonogashira\u53cd\u5e94\u5219\u7528\u50ac\u5316\u91cf\u7684\u94af\u548c\u94dc\u50ac\u5316\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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